dc.contributor.author |
Ratner V. |
|
dc.contributor.author |
Isaeva Z. |
|
dc.contributor.author |
Arbuzov B. |
|
dc.date.accessioned |
2018-09-14T20:23:49Z |
|
dc.date.available |
2018-09-14T20:23:49Z |
|
dc.date.issued |
1969 |
|
dc.identifier.issn |
0568-5230 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/132427 |
|
dc.description.abstract |
1. The oxidation of 3-carene with P (OAc)4 in acetic acid was studied. The following were found in the reaction products: m-methylisopropenylbenzene; 3,6,6-trimethylcycloheptadiene-2,4-one-1; 3-acetyl-6,6-dimethylbicyclo-[3,1,0]-hexane; the acetate of carene-4(7)-ol-3; an acetate with the presumed structure of the acetate of p-menthadiene-1,8(9)-ol-5; the acetate of 2-m-tolylpropanol-2; the acetate of trans-2,4-caranediol. 2. During the reaction there are rearrangements of the carene structure to p- and m-menthadiene, bicyclo-[3,1,0]-hexane, and cycloheptadiene systems. 3. The difference in the course of the oxidation of 3-carene with Pb(OAc)4 in acetic acid and in benzene was obtained by the influence of temperature and solvent. © 1970 Consultants Bureau. |
|
dc.relation.ispartofseries |
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science |
|
dc.title |
Oxidation of 3-carene by lead tetraacetate in acetic acid |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
12 |
|
dc.relation.ispartofseries-volume |
18 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
2596 |
|
dc.source.id |
SCOPUS05685230-1969-18-12-SID34250476583 |
|