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dc.contributor.author | Arbuzov B. | |
dc.contributor.author | Vinogradova V. | |
dc.contributor.author | Polezhaeva N. | |
dc.date.accessioned | 2018-09-14T20:20:01Z | |
dc.date.available | 2018-09-14T20:20:01Z | |
dc.date.issued | 1961 | |
dc.identifier.issn | 0568-5230 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/132357 | |
dc.description.abstract | 1. The reaction of triethyl phosphite with 2,6-dibromocyclohexanone follows a complex course. In addition to the expected diethylphosphoric ester of the enol form of the ester of cyclohexanone-2-phosphonic-1 acid, by-products are formed which are produced by conversions of the latter compound (diethyl ester of cyclohexanone-2-phosphonic-1 acid and tetraethyl ester of hypophosphoric acid), and also an intermediate product, diethyl bromo-6-cyclohexen-1-yl phosphoric ester [diethylcyclohexadien-1,5-yl phosphate, diethyl phenyl phosphate]. 2. The cis- and trans-isomers of 2,6-dibromocyclohexanone react differently with triethyl phosphite. The trans-isomer gives the diethylphosphoric ester of the enol form of the ester of cyclohexanone-2-phosphonic-1 acid as the main reaction product. With the cis-form the diethyl ester of cyclohexanone-2-phosphonic-1 acid is formed. In both cases, the products enumerated in paragraph 1 also are obtained. © 1962 Consultants Bureau Enterprises, Inc. | |
dc.relation.ispartofseries | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science | |
dc.title | Esters of β-ketophosphonic acids - Communication 8. Reaction of 2,6-dibromocyclohexanone with triethyl phosphite | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 11 | |
dc.relation.ispartofseries-volume | 10 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 1877 | |
dc.source.id | SCOPUS05685230-1961-10-11-SID34250607613 |