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β-Keto phosphonic esters Communication 3. Structures of the products of the reaction of some halo ketones with triethyl phosphite and with sodium diethyl phosphite

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dc.contributor.author Arbuzov B.
dc.contributor.author Vinogradova V.
dc.contributor.author Polezhaeva N.
dc.date.accessioned 2018-09-14T20:19:12Z
dc.date.available 2018-09-14T20:19:12Z
dc.date.issued 1959
dc.identifier.issn 0568-5230
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/132342
dc.description.abstract 1. Reaction of triethyl phosphite with chloro- and bromo-acetones* and 1-bromo-2-butanone gives the corresponding β-keto phosphonic esters. 2. The products obtained by methylating the potassium derivatives of diethyl acetonylphosphonate and of diethyl 1-methylacetonylphosphonate with methyl iodide are sB-keto phosphonic esters. 3. Reaction of sodium diethyl phosphite with chloro- and bromo-acetones and 3~bromo-2-butanone gives epoxy phosphonic esters. The structures of these were proved by confirmatory synthesis and by analysis of their Raman spectra. 4. In spite of Kreutzkamp and Kayser's results, reaction of sodium diethyl phosphite with chloro- or bromoacetone does not give an unsaturated ester (diethyl isopropenyl phosphate); the products are diethyl epoxy-1-methylethylphosphonate and diethyl acetonylphosphonate. 5. The product of the reaction of 5-chloro-2-pentanone with sodium diethyl phosphite is diethyl tetrahydro2-methyl-2-furylphosphonate. © 1959 Consultants Bureau Inc.
dc.relation.ispartofseries Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
dc.title β-Keto phosphonic esters Communication 3. Structures of the products of the reaction of some halo ketones with triethyl phosphite and with sodium diethyl phosphite
dc.type Article
dc.relation.ispartofseries-issue 1
dc.relation.ispartofseries-volume 8
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 37
dc.source.id SCOPUS05685230-1959-8-1-SID34250594404


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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