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dc.contributor.author | Kirmse R. | |
dc.contributor.author | Dietzsch W. | |
dc.contributor.author | Solov'ev B. | |
dc.date.accessioned | 2018-09-14T20:12:03Z | |
dc.date.available | 2018-09-14T20:12:03Z | |
dc.date.issued | 1977 | |
dc.identifier.issn | 0022-1902 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/132215 | |
dc.description.abstract | A first single crystal EPR study of a Pt3+ chelate-tetrabutylammonium-bis (maleonitriledithiolato) platinate (III)-diamagnetically diluted by the corresponding gold (III) chelate is reported. The spectra are described by a rhombic spin Hamiltonian. For some orientations of the magnetic field 33S superhyperfine splitting was observed. The 33S tensor has the maximum value perpendicular to the plane of the complex supporting a 2B3g ground state in which the half-filled out-of-plane π molecular orbital is extensively delocalized over the ligands. Furthermore, the electron spin-lattice relaxation of the Pt3+ complex was measured in the temperature range 4.2 ≤ T ≤ 16 K. Spin-lattice interactions were found to be mainly responsible for the linewidth in the Pt3+ spectra, which is larger by a factor 2 than those observed for Pd3+ and Ni3+ in the same host complex [Au(mnt)2]-. © 1977. | |
dc.relation.ispartofseries | Journal of Inorganic and Nuclear Chemistry | |
dc.title | A single crystal EPR study of the platinum (III)-bis (maleonitriledithiolate)-monoanion | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 7 | |
dc.relation.ispartofseries-volume | 39 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 1157 | |
dc.source.id | SCOPUS00221902-1977-39-7-SID49349132177 |