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Experimental proof that the Diels-Alder reaction of tetracyanoethylene with 9,10-dimethylanthracene passes through formation of a complex between the reactants

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dc.contributor.author Kiselev V.
dc.contributor.author Miller J.
dc.date.accessioned 2018-09-14T20:04:44Z
dc.date.available 2018-09-14T20:04:44Z
dc.date.issued 1975
dc.identifier.issn 0002-7863
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/132100
dc.description.abstract Up to the present, it has been considered impossible to determine kinetically whether the complex often formed between diene and dienophile is a true intermediate in the Diels-Alder reaction. A method based on the effect of temperature on the reaction rates has been tested and found successful in proving that the complex formed by tetracyanoethylene and 9,10-dimethylanthracene is indeed a true intermediate in the Diels-Alder reaction of those molecules.
dc.relation.ispartofseries Journal of the American Chemical Society
dc.title Experimental proof that the Diels-Alder reaction of tetracyanoethylene with 9,10-dimethylanthracene passes through formation of a complex between the reactants
dc.type Article
dc.relation.ispartofseries-issue 14
dc.relation.ispartofseries-volume 97
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 4036
dc.source.id SCOPUS00027863-1975-97-14-SID0000430460


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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