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P-tert-Butylthiacalix[4]arenes functionalized by N-(4'-nitrophenyl)acetamide and N,N-diethylacetamide fragments: Synthesis and binding of anionic guests

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dc.contributor.author Vavilova A.
dc.contributor.author Stoikov I.
dc.date.accessioned 2018-04-05T07:10:17Z
dc.date.available 2018-04-05T07:10:17Z
dc.date.issued 2017
dc.identifier.uri http://dspace.kpfu.ru/xmlui/handle/net/130344
dc.description.abstract © 2017 Vavilova and Stoikov; Licensee Beilstein-Institut. New p-tert-butylthiacalix[4]arenes, which are mono-, 1,2-di- and tetrasubstituted at the lower rim containing N-(4'- nitrophenyl)acetamide and N,N-diethylacetamide groups in cone and partial cone conformations have been synthesized. Their complexation ability towards a number of tetrabutylammonium salts n-Bu 4 NX (X = F - , Cl - , Br - , I - , CH 3 CO 2 -, H 2 PO 4 - , NO 3 - ) was studied by UV spectroscopy. The effective receptor for the anions studied as well as selective receptors for F-, CH 3 CO 2 - and H 2 PO 4 - ions, which based on the synthesized thiacalix[4]arenes, have been obtained. It was shown that p-tertbutylthiacalix[ 4] arene tetrasubstituted at the lower rim by N-(4'-nitrophenyl)acetamide moieties bonded to the anions studied with association constants within the range of 3.55 × 10 3 -7.94 × 10 5 M -1 . Besides, the binding selectivity for F - , Cl - , CH 3 CO 2 - , and H 2 PO 4 - anions against other anions was in the range of 4.1-223.9. Substituting one or two fragments in the macrocycle with N,Ndiethylacetamide groups significantly reduces the complexation ability of the receptor. In contrast to the 1,3-disubstituted macrocycle containing two N-(4'-nitrophenyl)acetamide moieties, the 1,2-disubstituted thiacalix[4]arene, which contains only one such fragment and a N,N-diethylacetamide moiety, selectively binds F - anions.
dc.subject Anion binding
dc.subject Synthesis
dc.subject Thiacalixarenes
dc.subject UV spectroscopy
dc.title P-tert-Butylthiacalix[4]arenes functionalized by N-(4'-nitrophenyl)acetamide and N,N-diethylacetamide fragments: Synthesis and binding of anionic guests
dc.type Article
dc.relation.ispartofseries-volume 13
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1940
dc.source.id SCOPUS-2017-13-SID85029737228


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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