Accuracy of determination of self-diffusion coefficients in studies of porphyrin-based complexes by 2D DOSY

dc.contributor.author	Khodov I.
dc.date.accessioned	2018-04-05T07:10:14Z
dc.date.available	2018-04-05T07:10:14Z
dc.date.issued	2017
dc.identifier.issn	1998-9539
dc.identifier.uri	http://dspace.kpfu.ru/xmlui/handle/net/130302
dc.description.abstract	© ISUCT Publishing. Influence of chemical exchange processes on the accuracy of determination of self-diffusion complexes of porphyrinnickel complexes was shown. A method of estimating the inaccuracy of the self-diffusion coefficients for an inverted porphyrin complex was proposed. The values obtained using two different approaches to recording DOSY spectra, STE and CPMG, were compared. Allowing for exchange was shown to be important for accurate diffusion measurements and correct interpretation of results obtained in studied of molecular-level processes.
dc.relation.ispartofseries	Macroheterocycles
dc.subject	2D DOSY
dc.subject	Chemical exchange
dc.subject	J-modulation
dc.subject	N-confused porphyrins
dc.subject	NMR
dc.subject	Self-diffusion coefficients
dc.title	Accuracy of determination of self-diffusion coefficients in studies of porphyrin-based complexes by 2D DOSY
dc.type	Article
dc.relation.ispartofseries-issue	3
dc.relation.ispartofseries-volume	10
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	313
dc.source.id	SCOPUS19989539-2017-10-3-SID85038111591

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.