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Synthesis and inner-sphere hydrophosphorylation of (η<sup>1</sup>-N)-N-benzyl-N-(1,3-dimethylbut-2-enylidene)amine-(dicarbonyl)(1,3,5-triorganyl-1,3,5-triazacyclohexane) molybdenum(0) and -tungsten(0)

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dc.contributor.author Kuramshin A.
dc.contributor.author Kolpakova E.
dc.contributor.author Galimullin R.
dc.contributor.author Galkin V.
dc.date.accessioned 2018-04-05T07:09:38Z
dc.date.available 2018-04-05T07:09:38Z
dc.date.issued 2017
dc.identifier.issn 1070-3632
dc.identifier.uri http://dspace.kpfu.ru/xmlui/handle/net/129877
dc.description.abstract © 2017, Pleiades Publishing, Ltd. Complexes of group VIb metals (Mo and W) has been prepared with N-benzyl-(3-methylbut-2-enylidene)amine, where the latter is coordinated with the dicarbonyl(1,3,5-triorganyl-1,3,5-triazacyclohexane)-metal(0) fragment exclusively through the lone electron pair of the imine nitrogen atom. The reactions of the synthesized metal complexes with diethyl phosphite in various conditions always involved the addition of the phosphite across the С=N bond to form, depending on the conditions, aminophosphonates or their inner-sphere rearrangement products amidophosphates. Both organophosphorus compounds remain in the coordination sphere of the transition metal complex.
dc.relation.ispartofseries Russian Journal of General Chemistry
dc.subject 1,3,5-triorganyl-1,3,5-triazacyclohexanes
dc.subject amidophosphate
dc.subject aminophosphonate
dc.subject conjugated imines
dc.subject group VIb metals
dc.subject inner-sphere hydrophosphorylation
dc.title Synthesis and inner-sphere hydrophosphorylation of (η<sup>1</sup>-N)-N-benzyl-N-(1,3-dimethylbut-2-enylidene)amine-(dicarbonyl)(1,3,5-triorganyl-1,3,5-triazacyclohexane) molybdenum(0) and -tungsten(0)
dc.type Article
dc.relation.ispartofseries-issue 9
dc.relation.ispartofseries-volume 87
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 2006
dc.source.id SCOPUS10703632-2017-87-9-SID85031902030


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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