Electrochemical amination of benzene in aqueous-acetic solutions of sulfuric acid

dc.contributor.author	Lisitsyn Y.
dc.contributor.author	Sukhov A.
dc.date.accessioned	2018-04-05T07:09:38Z
dc.date.available	2018-04-05T07:09:38Z
dc.date.issued	2017
dc.identifier.issn	1070-3632
dc.identifier.uri	http://dspace.kpfu.ru/xmlui/handle/net/129871
dc.description.abstract	© 2017, Pleiades Publishing, Ltd. Indirect cathodic amination of benzene with hydroxylamine in the presence of Ti(IV)/Ti(III) mediator system in aqueous media containing 4–11 mol/L H 2 SO 4 and 13–5.5 mol/L AcOH has been studied. Aniline, diphenyl, and isomeric phenylenediamines are the electrolysis products at 25–60°C. The increase in temperature favors the formation of the monoamino compound. Aniline yield with respect to hydroxylamine at complete conversion of the latter has reached 78.7%, mass fraction of aniline being 97.1%.
dc.relation.ispartofseries	Russian Journal of General Chemistry
dc.subject	aniline
dc.subject	benzene
dc.subject	cathode
dc.subject	cation-radical aromatic substitution
dc.subject	hydroxylamine
dc.subject	Ti(IV)/Ti(III) mediator system
dc.title	Electrochemical amination of benzene in aqueous-acetic solutions of sulfuric acid
dc.type	Article
dc.relation.ispartofseries-issue	5
dc.relation.ispartofseries-volume	87
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	929
dc.source.id	SCOPUS10703632-2017-87-5-SID85021120401

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Публикации сотрудников КФУ Scopus [24551]
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