Electrochemical amination. Selective introduction of two amino groups into an aromatic ring

dc.contributor.author	Lisitsyn Y.
dc.contributor.author	Sukhov A.
dc.date.accessioned	2018-04-05T07:09:38Z
dc.date.available	2018-04-05T07:09:38Z
dc.date.issued	2017
dc.identifier.issn	1070-3632
dc.identifier.uri	http://dspace.kpfu.ru/xmlui/handle/net/129870
dc.description.abstract	© 2017, Pleiades Publishing, Ltd. Indirect cathodic amination of anisole via a Ti(IV)–NH 2 OH system in aqueous solutions of sulfuric acid is studied. The major products of the radical cation substitution in these media are para- and ortho-anisidines and 4-methoxy-1,3-phenylenediamine. The most efficient electrochemical process takes place in 10–12 М H 2 SO 4 . Under these conditions, complete conversion of the source of amino radicals is observed, and the total current yields, which correspond to the yields per hydroxylamine, reach 60%.
dc.relation.ispartofseries	Russian Journal of General Chemistry
dc.subject	4-methoxy-1,3-phenylenediamine
dc.subject	anisole
dc.subject	cathode
dc.subject	hydroxylamine
dc.subject	radical cation aromatic substitution
dc.subject	Ti(IV)/Ti(III) mediator system
dc.title	Electrochemical amination. Selective introduction of two amino groups into an aromatic ring
dc.type	Article
dc.relation.ispartofseries-issue	1
dc.relation.ispartofseries-volume	87
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	16
dc.source.id	SCOPUS10703632-2017-87-1-SID85021706182

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Публикации сотрудников КФУ Scopus [24551]
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