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dc.contributor.author | Lisitsyn Y. | |
dc.contributor.author | Sukhov A. | |
dc.date.accessioned | 2018-04-05T07:09:38Z | |
dc.date.available | 2018-04-05T07:09:38Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 1070-3632 | |
dc.identifier.uri | http://dspace.kpfu.ru/xmlui/handle/net/129870 | |
dc.description.abstract | © 2017, Pleiades Publishing, Ltd. Indirect cathodic amination of anisole via a Ti(IV)–NH 2 OH system in aqueous solutions of sulfuric acid is studied. The major products of the radical cation substitution in these media are para- and ortho-anisidines and 4-methoxy-1,3-phenylenediamine. The most efficient electrochemical process takes place in 10–12 М H 2 SO 4 . Under these conditions, complete conversion of the source of amino radicals is observed, and the total current yields, which correspond to the yields per hydroxylamine, reach 60%. | |
dc.relation.ispartofseries | Russian Journal of General Chemistry | |
dc.subject | 4-methoxy-1,3-phenylenediamine | |
dc.subject | anisole | |
dc.subject | cathode | |
dc.subject | hydroxylamine | |
dc.subject | radical cation aromatic substitution | |
dc.subject | Ti(IV)/Ti(III) mediator system | |
dc.title | Electrochemical amination. Selective introduction of two amino groups into an aromatic ring | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 1 | |
dc.relation.ispartofseries-volume | 87 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 16 | |
dc.source.id | SCOPUS10703632-2017-87-1-SID85021706182 |