Determination of the reaction acceleration effect at an elevated hydrostatic pressure

Abstract

© 2017, Springer Science+Business Media, LLC. A method was proposed for the calculation of changes in the rate (k P /k P=0 ) and equilibrium constants (K P /K P=0 ) for chemical reactions under high hydrostatic pressure (10—20 kbar). The calculation based on the activation and reaction volume data makes it possible to select optimum conditions for slow and equilibrium chemical processes.