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dc.contributor.author | Puls F. | |
dc.contributor.author | Richter N. | |
dc.contributor.author | Kataeva O. | |
dc.contributor.author | Knölker H. | |
dc.date.accessioned | 2018-04-05T07:09:26Z | |
dc.date.available | 2018-04-05T07:09:26Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 0947-6539 | |
dc.identifier.uri | http://dspace.kpfu.ru/xmlui/handle/net/129736 | |
dc.description.abstract | © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim We have developed a short and simple synthesis of tetranuclear palladium(II) complexes that have been structurally confirmed by X-ray analysis. These complexes were formed in about 30 % overall yield by spontaneous metalation of dimethylaminoarene derivatives and exhibit a high stability. We have studied the utility of the tetranuclear palladium(II) complexes as precatalysts for Mizoroki–Heck and Suzuki–Miyaura cross-coupling reactions. Our novel complexes show excellent catalytic activities with high turnover numbers (TON) and high turnover frequencies (TOF) (e.g., for the Suzuki–Miyaura reaction: TON up to 538000 and TOF up to 23400 h −1 at room temperature). | |
dc.relation.ispartofseries | Chemistry - A European Journal | |
dc.subject | catalysis | |
dc.subject | Mizoroki–Heck coupling | |
dc.subject | palladacycles | |
dc.subject | Suzuki–Miyaura coupling | |
dc.subject | X-ray diffraction | |
dc.title | Synthesis of Tetranuclear Palladium(II) Complexes and Their Catalytic Activity for Cross-Coupling Reactions | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 69 | |
dc.relation.ispartofseries-volume | 23 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 17576 | |
dc.source.id | SCOPUS09476539-2017-23-69-SID85034264916 |