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Cesium and americium extraction from carbonate-alkaline media with O-substituted p-alkylcalix[8]arenes

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dc.contributor.author Smirnov I.
dc.contributor.author Stepanova E.
dc.contributor.author Ivenskaya N.
dc.contributor.author Karavan M.
dc.contributor.author Zaripov S.
dc.contributor.author Kleshnina S.
dc.contributor.author Solovieva S.
dc.contributor.author Antipin I.
dc.date.accessioned 2018-04-05T07:09:16Z
dc.date.available 2018-04-05T07:09:16Z
dc.date.issued 2017
dc.identifier.issn 0236-5731
dc.identifier.uri http://dspace.kpfu.ru/xmlui/handle/net/129622
dc.description.abstract © 2017, Akadémiai Kiadó, Budapest, Hungary. 137 Cs and 241 Am extraction with perchloroethylene solutions of O-substituted p-alkylcalix[8]arenes (alkyl: tert-butyl, iso-nonyl) from carbonate-alkaline media is studied. Dependence of distribution ratios on pH values of the aqueous phase in the range 11–13.9 and on the nature of functional groups in the calixarene platform is confirmed. Composition of cesium and americium solvates with calix[8] arenes is determined. Tert-butylcalix[8]arene with oxybis(ethane-1,2-diyl) bridging group possesses superior efficiency towards cesium in alkaline media. The most efficient extractants for americium are “mixed” iso-nonyl-tert-butylcalix[8] arenes with ethane-1,2-diyl and oxybis(ethane-1,2-diyl) bridging groups.
dc.relation.ispartofseries Journal of Radioanalytical and Nuclear Chemistry
dc.subject 137 Cs
dc.subject 241 Am
dc.subject Alkaline medium
dc.subject Extraction
dc.subject O-substituted calix[8]arenes
dc.title Cesium and americium extraction from carbonate-alkaline media with O-substituted p-alkylcalix[8]arenes
dc.type Article
dc.relation.ispartofseries-issue 2
dc.relation.ispartofseries-volume 314
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1257
dc.source.id SCOPUS02365731-2017-314-2-SID85030122533


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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