Thermodynamics of imidazolium based ionic liquids with cyano containing anions

dc.contributor.author	Zaitsau D.
dc.contributor.author	Pohako-Esko K.
dc.contributor.author	Arlt S.
dc.contributor.author	Emel'yanenko V.
dc.contributor.author	Schulz P.
dc.contributor.author	Wasserscheid P.
dc.contributor.author	Schulz A.
dc.contributor.author	Verevkin S.
dc.date.accessioned	2018-04-05T07:09:15Z
dc.date.available	2018-04-05T07:09:15Z
dc.date.issued	2017
dc.identifier.issn	0167-7322
dc.identifier.uri	http://dspace.kpfu.ru/xmlui/handle/net/129603
dc.description.abstract	© 2017 Elsevier B.V. Thermochemical investigation of the series of 1-alkyl-3-methylimidazolium ionic liquids with B(CN) 4 and PF 2 (CN) 4 anions is presented. Absolute vapor pressures and vaporization enthalpies have been measured by using quartz-crystal microbalance. Gas-phase enthalpies of formation of ILs were calculated by using the high-level quantum-chemical method G3MP2. From a combination of experimental and theoretical results, the enthalpy of formation of aqueous B(CN) 4 ion was derived for the first time.
dc.relation.ispartofseries	Journal of Molecular Liquids
dc.subject	Enthalpy of formation
dc.subject	Enthalpy of vaporization
dc.subject	Ionic liquid
dc.subject	Vapor pressure
dc.title	Thermodynamics of imidazolium based ionic liquids with cyano containing anions
dc.type	Article
dc.relation.ispartofseries-volume	248
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	86
dc.source.id	SCOPUS01677322-2017-248-SID85030987402

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