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dc.contributor.author | Yagofarov M. | |
dc.contributor.author | Nagrimanov R. | |
dc.contributor.author | Solomonov B. | |
dc.date.accessioned | 2018-04-05T07:09:12Z | |
dc.date.available | 2018-04-05T07:09:12Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 0040-6031 | |
dc.identifier.uri | http://dspace.kpfu.ru/xmlui/handle/net/129576 | |
dc.description.abstract | © 2017 Elsevier B.V. In this work a solution calorimetry approach was applied for determination of the sublimation enthalpies of 9 substituted acetanilides. The solution enthalpies of acetanilide and 9 its derivatives in acetonitrile were measured and solvation enthalpies were calculated by a group-additivity scheme. Additivity of solvation enthalpy due to influence of the substituent on the acidity of the proton of NHCOCH 3 -group and OH-group was checked with the use of IR-spectroscopy. The sublimation enthalpies obtained from the solution calorimetry approach were compared to the available literature data. In most cases convergence within the limits of experimental uncertainty was demonstrated. | |
dc.relation.ispartofseries | Thermochimica Acta | |
dc.subject | Acetanilides | |
dc.subject | Enthalpy of solution | |
dc.subject | Enthalpy of solvation | |
dc.subject | Enthalpy of sublimation | |
dc.title | Sublimation enthalpies of 9 substituted acetanilides at 298 K estimated by solution calorimetry approach | |
dc.type | Article | |
dc.relation.ispartofseries-volume | 656 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 85 | |
dc.source.id | SCOPUS00406031-2017-656-SID85029006343 |