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Coordination Polymers based on calixarene derivatives: Structures and properties

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dc.contributor.author Ovsyannikov A.
dc.contributor.author Solovieva S.
dc.contributor.author Antipin I.
dc.contributor.author Ferlay S.
dc.date.accessioned 2018-04-05T07:08:53Z
dc.date.available 2018-04-05T07:08:53Z
dc.date.issued 2017
dc.identifier.issn 0010-8545
dc.identifier.uri http://dspace.kpfu.ru/xmlui/handle/net/129394
dc.description.abstract © 2017 Elsevier B.V. The solid-state structures of 1D–3D Coordination Polymers based on the macrocyclic calixarene backbone have been reviewed, based on the chemical nature of appended substituents on the macrocycle platform. The coordination propensity of this class of ligands is analysed, taking into account the different coordinating atoms/groups that can be located on the macrocyclic ligand: (1) the unmodified inherently coordinating thiacalix[4]arene with the S bridges as donor atoms; (2) different conformations of calix[n] arene units, with appended O donor atoms; (3) the chemical modification of the upper rim of calix[n]arenes and thiacalix[n] arenes, with coordinating groups, in particular the use of the sulfonate groups; (4) calix[4]arenes, thiacalix[4] arenes and tetramercaptothiacalix[4]rene that have been modified at their lower rim (mono, di and tetra substitution) with coordinating groups like cyano, carboxylate, pyridyl and pyrazolyl groups. All the formed coordination networks have been described. A special attention has been drawn to the structural and functional properties of these extended networks: magnetic, luminescence, adsorption and catalytic properties. Perspectives and future challenges in this emerging field are also discussed.
dc.relation.ispartofseries Coordination Chemistry Reviews
dc.subject Calixarene skeleton
dc.subject Calix[4]arene
dc.subject Calix[n]arene
dc.subject Coordination bonds
dc.subject Extended Coordination Polymers
dc.subject Luminescent properties
dc.subject Magnetic properties
dc.subject Metallic cations
dc.subject Sorption properties
dc.subject Tetramercaptothiacalix[4]arene
dc.subject Thiacalix[4]arene
dc.title Coordination Polymers based on calixarene derivatives: Structures and properties
dc.type Review
dc.relation.ispartofseries-volume 352
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 151
dc.source.id SCOPUS00108545-2017-352-SID85034112699


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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