Electrolysis of the system Ti(IV)-NH 2OH-C 6H 6 in an 11 M H 2SO 4 solution shows that using an organic solvent (acetic acid, acetonitrile) during cathodically initiated amination of aromatic substrates permits the production ...
Indirect cathode amination of anisole with Ti(IV)/Ti(III) and NH 2OH in media containing 4 or 6 M H2SO4, CH 3CN, and H2O (in small amounts) was studied. Para- and ortho-anisidines were the major products of radical cation ...
The electrochemical amination of anisole in 4.0-6.0 M H 2SO 4 solutions containing CH 3COOH and small amounts of water is studied with the use of the Ti(IV)/Ti(III)-NH 2OH system. Under these conditions, the products of ...
Electrochemical amination of benzene in sulfuric acid electrolytes is studied and experimental conditions for highly efficient synthesis of primary aromatic amino compounds are determined. In the electrolysis of Ti(IV)-NH ...