Browsing by Author "Kagirov R."

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  • Activation and transformation of white phosphorus by palladium(ii) complexes 
    Kagirov R.; Voloshin A.; Rizvanov I.; Sinyashin O.; Yakhvarov D. (2010)
    A reaction of bis(triphenylphosphine)palladium dibromide with white phosphorus in the presence of NaBPh4 selectively gives phosphorous acid H3PO3. The mechanism of the formation involves coordination of a white phosphorus ...
  • Electrochemical reactions of white phosphorus 
    Yakhvarov D.; Gorbachuk E.; Kagirov R.; Sinyashin O. (2012)
    The main electrochemical transformations of elemental (white) phosphorus were considered. Special attention was given to the recently developed processes of preparation of organophosphorus compounds (OPCs) with phosphorus-carbon ...
  • Selective synthesis of nanosized palladium phosphides from white phosphorus 
    Kagirov R.; Voloshin A.; Kadirov M.; Nizameev I.; Sinyashin O.; Yakhvarov D. (2011)
    The reaction of white phosphorus with the palladium(0) complex [Pd 2(dba)3] (dba is dibenzylideneacetone) leads to stable associates [Pd(P4)]n. The coordination polymer obtained is stabilized in a solid state via the ...

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