© 2017 American Chemical Society. Guest exchange in clathrates is a complex activated phenomenon of the guest-host cage interaction on the molecular-scale level. To model this process, we develop a mathematical description ...

© 2015 American Chemical Society. The shrinking-core model of the formation of gas hydrates from ice spheres with well-defined geometry gives experimental access to the gas permeation in bulk hydrates which is relevant to ...

The shrinking-core model of the formation of gas hydrates from ice spheres with a well-defined geometry gives experimental access to the gas permeation in bulk hydrates. Here we report on results obtained for CO2 clathration ...