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Heterospin complex showing spin transition at room temperature

Tolstikov S.; Artiukhova N.; Romanenko G.; Bogomyakov A.; Zueva E.; Barskaya I.; Fedin M.; Maryunina K.; Tretyakov E.; Sagdeev R.; Ovcharenko V. (2015)

© 2015 Elsevier Ltd. All rights reserved. New nitronyl nitroxides LMe and LMe-CP containing a 4-methylpyridin-3-yl substituent were synthesized. It was found that the interaction of Cu(hfac)<inf>2</inf> ...
Photoswitching of a thermally unswitchable molecular magnet Cu(hfac) 2Li-Pr evidenced by steady-state and time-resolved electron paramagnetic resonance

Barskaya I.; Tretyakov E.; Sagdeev R.; Ovcharenko V.; Bagryanskaya E.; Maryunina K.; Takui T.; Sato K.; Fedin M. (2014)

Most photoswitchable molecular magnets exhibit thermally induced switching, as is typical of spin crossover (SCO), valence tautomerism and SCO-like phenomena. We report a rare case of a copper-nitroxide based molecular ...
(Pyrrole-2,5-diyl)-bis(nitronyl nitroxide) and-bis(iminonitroxide): Specific features of the synthesis, structure, and magnetic properties

Tretyakov E.; Tkacheva A.; Romanenko G.; Bogomyakov A.; Stass D.; Maryasov A.; Zueva E.; Trofimov B.; Ovcharenko V. (2020)

© 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/ ...
Second-order nonlinear optical properties of composite material of an azo-chromophore with a tricyanodiphenyl acceptor in a poly(styrene-co-methyl methacrylate) matrix

Shelkovnikov V.; Selivanova G.; Lyubas G.; Korotaev S.; Shundrina I.; Tretyakov E.; Zueva E.; Plekhanov A.; Mikerin S.; Simanchuk A. (2017)

© 2017 Elsevier B.V.The composite material of new synthesized 4-((4-(N,N-n-dibutylamino) phenyl)diazenyl)-biphenyl-2,3,4-tricarbonitrile (GAS dye) in commercial poly(styrene-co-methyl methacrylate) (PSMMA) was prepared, ...
Stereo sensitivity of exchange interactions in NiII and CuII heterospin complexes with 5-formylpyrrolyl-substituted nitroxides

Zueva E.; Tretyakov E.; Fokin S.; Romanenko G.; Tkacheva A.; Bogomyakov A.; Petrova O.; Trofimov B.; Sagdeev R.; Ovcharenko V. (2016)

© 2016, Springer Science+Business Media New York.5-Formylpyrrolyl-substituted nitronyl and imino nitroxide radicals HL1 and HL2 were synthesized. Their solid phases are formed by packing pairs of the molecules. In the ...
Synthesis and study of CuII complex with nitroxide, a jumping crystal analog

Sagdeev R.; Tolstikov S.; Fokin S.; Obsharova I.; Tumanov S.; Veber S.; Romanenko G.; Bogomyakov A.; Fedin M.; Tretyakov E.; Halcrow M.; Ovcharenko V. (2017)

© 2017, Springer Science+Business Media, LLC. We synthesized 1-ethylimidazolyl-substituted nitronyl nitroxides, i.e., 2-(1-ethylimidazol-4-yl)- (L 4Et ) and 2-(1-ethylimidazol-5-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole ...

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