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New complexes of gadolinium with dicarboxylate diphosphabetaines
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| dc.contributor.author | Bakhtiyarov D.I. | |
| dc.contributor.author | Romanov S.R. | |
| dc.contributor.author | Hafizova A.I. | |
| dc.contributor.author | Shibaeva K.O. | |
| dc.contributor.author | Gerasimov A.V. | |
| dc.contributor.author | Bakhtiyarova Y.V. | |
| dc.contributor.author | Usupova L.M. | |
| dc.contributor.author | Galkina I.V. | |
| dc.date.accessioned | 2022-02-09T20:35:19Z | |
| dc.date.available | 2022-02-09T20:35:19Z | |
| dc.date.issued | 2021 | |
| dc.identifier.issn | 1042-6507 | |
| dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/169228 | |
| dc.description.abstract | The processes of complexation of dicarboxylate diphosphabetaines with gadolinium nitrate were studied, as a result of which stable polymer metal complexes insoluble in inorganic and organic solvents were obtained. To carry out these reactions, dicarboxylate diphosphabetaines were previously synthesized: 3,3'-(propane-1,3-diylbis (diphenyl)phosphoniondiyl)dipropanoate and 3,3'-(hexane-1,3-diylbis (diphenyl)phosphoniondiyl)dipropanoate, based on maleic acid with 1,3-bis(diphenylphosphino)bisphosphinspropane and 1,6-bis(diphenylphosphino)bisphosphinshexane. The structure of dicarboxylate diphosphabetaines and poly-nuclear polymer complexes of gadolinium has been confirmed by modern physical and chemical methods of research, including NMR and IR spectra, elemental and X-ray structural analysis, thermal stability has been studied by simultaneous thermogravimetry and differential scanning calorimetry. | |
| dc.relation.ispartofseries | Phosphorus, Sulfur and Silicon and the Related Elements | |
| dc.subject | dicarboxylate diphosphabetaines | |
| dc.subject | Gadolinium complexes | |
| dc.subject | tertiary phosphines | |
| dc.subject | thermal stability | |
| dc.subject | X-ray crystallography | |
| dc.title | New complexes of gadolinium with dicarboxylate diphosphabetaines | |
| dc.type | Article | |
| dc.collection | Публикации сотрудников КФУ | |
| dc.source.id | SCOPUS10426507-2021-SID85121335664 |
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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.