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Labile η<sup>6</sup>-areneruthenium sulfide clusters. Crystal structure of [(C<inf>6</inf>H<inf>6</inf>)<inf>4</inf>Ru<inf>5</inf>S<inf>4</inf>](PF<inf>6</inf>)<inf>2</inf> and [(C<inf>6</inf>H<inf>6</inf>)<inf>4</inf>Ru<inf>4</inf>S<inf>5</inf>](PF<inf>6</inf>)<inf>2</inf>
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| dc.contributor.author | Korenev V. | |
| dc.contributor.author | Abramov P. | |
| dc.contributor.author | Kompankov N. | |
| dc.contributor.author | Gushchin A. | |
| dc.contributor.author | Sheven D. | |
| dc.contributor.author | Sokolov M. | |
| dc.date.accessioned | 2019-01-22T20:33:10Z | |
| dc.date.available | 2019-01-22T20:33:10Z | |
| dc.date.issued | 2018 | |
| dc.identifier.issn | 0022-328X | |
| dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/147678 | |
| dc.description.abstract | © 2018 Elsevier B.V. A new labile areneruthenium sulfide complex, [(C6H6)3Ru3S2](PF6)2 (1), was prepared and characterized both in solid state and in solution. Light-driven de-coodination of the arene ligands has been demonstrated. Two new polynuclear areneruthenium complexes, [(C6H6)4Ru5S4](PF6)2·2CH3CN (2) and [(C6H6)4Ru4S5](PF6)2·1.25CH3CN·0.5H2O (3), were obtained from 1 and structurally characterized. Redox behaviour of [(C6H6)3Ru3S2](PF6)2 and [Ru5S4(C6H6)4](PF6)2·2CH3CN was studied by cyclic voltammetry and reveals one reversible reduction wave. | |
| dc.relation.ispartofseries | Journal of Organometallic Chemistry | |
| dc.subject | Areneruthenium complexes | |
| dc.subject | Electrochemistry | |
| dc.subject | Photoactivation | |
| dc.subject | Sulfide clusters | |
| dc.title | Labile η<sup>6</sup>-areneruthenium sulfide clusters. Crystal structure of [(C<inf>6</inf>H<inf>6</inf>)<inf>4</inf>Ru<inf>5</inf>S<inf>4</inf>](PF<inf>6</inf>)<inf>2</inf> and [(C<inf>6</inf>H<inf>6</inf>)<inf>4</inf>Ru<inf>4</inf>S<inf>5</inf>](PF<inf>6</inf>)<inf>2</inf> | |
| dc.type | Article | |
| dc.relation.ispartofseries-volume | 867 | |
| dc.collection | Публикации сотрудников КФУ | |
| dc.relation.startpage | 347 | |
| dc.source.id | SCOPUS0022328X-2018-867-SID85041352611 |
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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.