dc.contributor.author |
Korenev V. |
|
dc.contributor.author |
Abramov P. |
|
dc.contributor.author |
Kompankov N. |
|
dc.contributor.author |
Gushchin A. |
|
dc.contributor.author |
Sheven D. |
|
dc.contributor.author |
Sokolov M. |
|
dc.date.accessioned |
2019-01-22T20:33:10Z |
|
dc.date.available |
2019-01-22T20:33:10Z |
|
dc.date.issued |
2018 |
|
dc.identifier.issn |
0022-328X |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/147678 |
|
dc.description.abstract |
© 2018 Elsevier B.V. A new labile areneruthenium sulfide complex, [(C6H6)3Ru3S2](PF6)2 (1), was prepared and characterized both in solid state and in solution. Light-driven de-coodination of the arene ligands has been demonstrated. Two new polynuclear areneruthenium complexes, [(C6H6)4Ru5S4](PF6)2·2CH3CN (2) and [(C6H6)4Ru4S5](PF6)2·1.25CH3CN·0.5H2O (3), were obtained from 1 and structurally characterized. Redox behaviour of [(C6H6)3Ru3S2](PF6)2 and [Ru5S4(C6H6)4](PF6)2·2CH3CN was studied by cyclic voltammetry and reveals one reversible reduction wave. |
|
dc.relation.ispartofseries |
Journal of Organometallic Chemistry |
|
dc.subject |
Areneruthenium complexes |
|
dc.subject |
Electrochemistry |
|
dc.subject |
Photoactivation |
|
dc.subject |
Sulfide clusters |
|
dc.title |
Labile η<sup>6</sup>-areneruthenium sulfide clusters. Crystal structure of [(C<inf>6</inf>H<inf>6</inf>)<inf>4</inf>Ru<inf>5</inf>S<inf>4</inf>](PF<inf>6</inf>)<inf>2</inf> and [(C<inf>6</inf>H<inf>6</inf>)<inf>4</inf>Ru<inf>4</inf>S<inf>5</inf>](PF<inf>6</inf>)<inf>2</inf> |
|
dc.type |
Article |
|
dc.relation.ispartofseries-volume |
867 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
347 |
|
dc.source.id |
SCOPUS0022328X-2018-867-SID85041352611 |
|