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Complexes of non-lacunary Keggin- and Dawson-type polyoxometalates with Pb(ii): formation of 1D coordination polymers with different bonding modes

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dc.contributor.author Udalova L.
dc.contributor.author Adonin S.
dc.contributor.author Abramov P.
dc.contributor.author Korolkov I.
dc.contributor.author Yunoshev A.
dc.contributor.author Plyusnin P.
dc.contributor.author Sokolov M.
dc.date.accessioned 2018-09-19T21:07:15Z
dc.date.available 2018-09-19T21:07:15Z
dc.date.issued 2016
dc.identifier.issn 1144-0546
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/143620
dc.description.abstract © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.A new coordination polymer based on Keggin-type [SiW12O40]4- and Pb2+ ions, {Pb2(μ2-DMF)2(DMF)8(SiW12O40)} (1a), was prepared by a reaction between H4[SiW12O40] and Pb(NO3)2 in N,N-dimethylformamide (DMF). Varying the crystallization conditions, a complex with a slightly different coordination mode of the {Pb2} unit and solvate composition, {Pb2(μ2-DMF)2(DMF)8(SiW12O40)}·DMF (1b), can be obtained. The complex containing Well-Dawson polyoxoanions, {(Pb(μ2-DMF)3(DMF)6)(Pb(DMF)5)(P2W18O62)}·0.5DMF·1.3H2O (2), was prepared by a similar strategy.
dc.relation.ispartofseries New Journal of Chemistry
dc.title Complexes of non-lacunary Keggin- and Dawson-type polyoxometalates with Pb(ii): formation of 1D coordination polymers with different bonding modes
dc.type Article
dc.relation.ispartofseries-issue 12
dc.relation.ispartofseries-volume 40
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 9981
dc.source.id SCOPUS11440546-2016-40-12-SID84999751728


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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