Complexes of non-lacunary Keggin- and Dawson-type polyoxometalates with Pb(ii): formation of 1D coordination polymers with different bonding modes

dc.contributor.author	Udalova L.
dc.contributor.author	Adonin S.
dc.contributor.author	Abramov P.
dc.contributor.author	Korolkov I.
dc.contributor.author	Yunoshev A.
dc.contributor.author	Plyusnin P.
dc.contributor.author	Sokolov M.
dc.date.accessioned	2018-09-19T21:07:15Z
dc.date.available	2018-09-19T21:07:15Z
dc.date.issued	2016
dc.identifier.issn	1144-0546
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/143620
dc.description.abstract	© The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.A new coordination polymer based on Keggin-type [SiW12O40]4- and Pb2+ ions, {Pb2(μ2-DMF)2(DMF)8(SiW12O40)} (1a), was prepared by a reaction between H4[SiW12O40] and Pb(NO3)2 in N,N-dimethylformamide (DMF). Varying the crystallization conditions, a complex with a slightly different coordination mode of the {Pb2} unit and solvate composition, {Pb2(μ2-DMF)2(DMF)8(SiW12O40)}·DMF (1b), can be obtained. The complex containing Well-Dawson polyoxoanions, {(Pb(μ2-DMF)3(DMF)6)(Pb(DMF)5)(P2W18O62)}·0.5DMF·1.3H2O (2), was prepared by a similar strategy.
dc.relation.ispartofseries	New Journal of Chemistry
dc.title	Complexes of non-lacunary Keggin- and Dawson-type polyoxometalates with Pb(ii): formation of 1D coordination polymers with different bonding modes
dc.type	Article
dc.relation.ispartofseries-issue	12
dc.relation.ispartofseries-volume	40
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	9981
dc.source.id	SCOPUS11440546-2016-40-12-SID84999751728

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