Показать сокращенную информацию
dc.contributor.author | Safin D. | |
dc.contributor.author | Szyrwiel Ł. | |
dc.contributor.author | Baranov S. | |
dc.contributor.author | Sokolov F. | |
dc.contributor.author | Babashkina M. | |
dc.contributor.author | Kozlowski H. | |
dc.date.accessioned | 2018-09-18T20:22:15Z | |
dc.date.available | 2018-09-18T20:22:15Z | |
dc.date.issued | 2008 | |
dc.identifier.issn | 1387-7003 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/139174 | |
dc.description.abstract | Reaction of N-phosphorylated thioureas RNHC(S)NHP(O)(OiPr)2 (R = tBu, HLI; R = Ph, HLII; R = 4′-benzo-15-crown-5, HLIII) with Pd(PhCN)2Cl2 in acetonitrile leads to complexes of formulae Pd(HLI-S)2Cl2 (1), Pd(HLII-S)2Cl2 (2) and Pd(HLIII-S)2Cl2 (3). The crystal structure of complex 1 has been investigated by X-ray crystallography. It was established that the thiourea ligands are in a trans-configuration and the palladium(II) cation is coordinated by the sulfur atoms of the C{double bond, long}S groups and the chlorine atoms. Complex 1 is the first example of palladium(II) complex in which the potentially chelating N-phosphorylated thiourea ligand is bound through the sulfur atom only. © 2008 Elsevier B.V. All rights reserved. | |
dc.relation.ispartofseries | Inorganic Chemistry Communications | |
dc.subject | Complex | |
dc.subject | Crown-ether | |
dc.subject | Monodentate coordination | |
dc.subject | Palladium(II) | |
dc.subject | Thiourea | |
dc.title | Intramolecular hydrogen bond controlled monodentate S-coordination of N-phosphoryl-N′-(R)-thioureas with Pd(II) | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 3 | |
dc.relation.ispartofseries-volume | 11 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 330 | |
dc.source.id | SCOPUS13877003-2008-11-3-SID39649092696 |