dc.contributor.author |
Rubanov A. |
|
dc.contributor.author |
Devyatov F. |
|
dc.date.accessioned |
2018-09-18T20:17:34Z |
|
dc.date.available |
2018-09-18T20:17:34Z |
|
dc.date.issued |
2010 |
|
dc.identifier.issn |
1066-5285 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/138381 |
|
dc.description.abstract |
A joint study using polarimetry, spectrophotometry, and mathematical modeling revealed the formation of 1: 1, 2: 1, and 4: 4 outer-sphere complexes of nickel(II) ions with neutral D-glucitol (H 6Glc-ol), viz., {[Ni(H 2O) n]•(H 6Glc-ol)aq} 2+, {[Ni(H 2O) n] 2•(H 6Glc-ol)aq} 4+, and {[Ni(H 2O) n] 4•[(H 6Glc-ol)aq] 4} 8+ in a weakly acidic medium. In aqueous solutions, D-glucitol forms tetramers. For each form, the constant of formation and the specific optical rotation was calculated. © 2010 Springer Science+Business Media, Inc. |
|
dc.relation.ispartofseries |
Russian Chemical Bulletin |
|
dc.subject |
aqueous solution |
|
dc.subject |
association |
|
dc.subject |
cluster |
|
dc.subject |
D-glucitol |
|
dc.subject |
equilibrium constants |
|
dc.subject |
mathematical modeling |
|
dc.subject |
nickel(II) |
|
dc.subject |
optical activity |
|
dc.subject |
outer-sphere complexation |
|
dc.subject |
tetramer |
|
dc.title |
The association and complexation equilibria in the system D-glucitol-nickel(II)-water |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
8 |
|
dc.relation.ispartofseries-volume |
59 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1594 |
|
dc.source.id |
SCOPUS10665285-2010-59-8-SID79951750117 |
|