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Electrochemically driven molecular rotors based on ferrocene-1,1'-diyl-bisphosphinic acids

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dc.contributor.author Yanilkin V.
dc.contributor.author Nasybullin G.
dc.contributor.author Nastapova N.
dc.contributor.author Madzhidov T.
dc.contributor.author Latypova L.
dc.contributor.author Morozov V.
dc.contributor.author Shekurov R.
dc.contributor.author Milyukov V.
dc.date.accessioned 2018-09-18T20:13:04Z
dc.date.available 2018-09-18T20:13:04Z
dc.date.issued 2015
dc.identifier.issn 1023-1935
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/137664
dc.description.abstract © 2015, Pleiades Publishing, Ltd. Based on ferrocene-1,1'-diyl-bisphosphinic acids Fc[P(R)(O)OH]<inf>2</inf> (R = H, Me, Et, Ph) in methanol, two types of electrochemically driven molecular rotors are developed. Monoanions of acids are fixed in the cis-conformation due to the presence of an intramolecular hydrogen bond, whereas dianions are fixed in the trans-conformation due to electrostatic repulsion forces. Upon the transformation of monoanions to dianions, the controlled rotation of cyclopentadienyl rings from cis to trans-conformation occurs; the reverse switching leads to the reverse rotation. In one type of rotors, the rotation is controlled by the reversible variation of the solution pH and composition in the electrochemical oxidation-re-reduction cycle of N-phe-nyl-N'-isopropyl-1,4-phenylenediamine; in the other type, the rotation is determined by the one electron oxidation-re-reduction of the ferrocene nucleus in monoanions. The latter rotor type at room temperature can operate stably only for a short time (τ< 1 s) and at longer times is irreversibly destructed during the oxidation stage.
dc.relation.ispartofseries Russian Journal of Electrochemistry
dc.subject electrochemistry
dc.subject ferrocene-1,1'-diyl-bisphophinic acid
dc.subject molecular rotor
dc.subject oxidation
dc.subject pH switching
dc.title Electrochemically driven molecular rotors based on ferrocene-1,1'-diyl-bisphosphinic acids
dc.type Article
dc.relation.ispartofseries-issue 7
dc.relation.ispartofseries-volume 51
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 645
dc.source.id SCOPUS10231935-2015-51-7-SID84938343862


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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