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Novel bicyclic hexanuclear copper(I) aggregate: Structure and solid state 31P CPMAS NMR spectra of [(Cu3L3)2] and [Cu(PPh3)2L] complexes of N-(diisopropoxythiophosphinyl)-N′-phenylthiourea (HL)

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dc.contributor.author Sokolov F.
dc.contributor.author Babashkina M.
dc.contributor.author Fayon F.
dc.contributor.author Rakhmatullin A.
dc.contributor.author Safin D.
dc.contributor.author Pape T.
dc.contributor.author Ekkehardt Hahn F.
dc.date.accessioned 2018-09-18T20:05:28Z
dc.date.available 2018-09-18T20:05:28Z
dc.date.issued 2009
dc.identifier.issn 0022-328X
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/136418
dc.description.abstract A new complex of N-thiophosphorylthiourea PhNHC(S)NHP(S)(OiPr)2 (HL) of formula [(Cu3L3)2] has been synthesized and characterized by single crystal X-ray diffraction, FT-IR, 1H, 31P NMR in solution and by 31P CPMAS NMR spectroscopy in the solid state. A comparison of the structure and the spectral parameters of [(Cu3L3)2] with those of the mononuclear analogue [Cu(PPh3)2L] was performed. In the solid state the aggregate [(Cu3L3)2] represents the first example of a spontaneous "side-by-side" association of two neutral cyclic [Cu3L3] moieties using two Cu-S-Cu bridges formed by the sulfur atoms of the PS-groups. The values of the 1J(31P-63,65Cu) and 2J(31P-31P) coupling constants of the [Cu(PPh3)2]+ moiety in the solid state spectra are reported. © 2008 Elsevier B.V. All rights reserved.
dc.relation.ispartofseries Journal of Organometallic Chemistry
dc.subject Copper(I) complexes
dc.subject Crystal structures
dc.subject MAS NMR spectroscopy
dc.subject N-Thiophosphorylthiourea
dc.subject Polynuclear complexes
dc.title Novel bicyclic hexanuclear copper(I) aggregate: Structure and solid state 31P CPMAS NMR spectra of [(Cu3L3)2] and [Cu(PPh3)2L] complexes of N-(diisopropoxythiophosphinyl)-N′-phenylthiourea (HL)
dc.type Article
dc.relation.ispartofseries-issue 2
dc.relation.ispartofseries-volume 694
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 167
dc.source.id SCOPUS0022328X-2009-694-2-SID57849084029


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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