dc.contributor.author |
Arbuzov B. |
|
dc.contributor.author |
Bogonostseva N. |
|
dc.contributor.author |
Vinogradova V. |
|
dc.contributor.author |
Batyrshin N. |
|
dc.date.accessioned |
2018-09-14T20:32:03Z |
|
dc.date.available |
2018-09-14T20:32:03Z |
|
dc.date.issued |
1976 |
|
dc.identifier.issn |
0568-5230 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/132550 |
|
dc.description.abstract |
1. 2-Methylindane-l,3-dione reacts with dialkylphosphorous acids in the presence of triethylamine at ∼20° with formation of 2-methyl-3-hydroxyindan-1-on-3-yl dialkylphosphonates. Upon further standing of the reaction mixture the latter isomerize to the corresponding phosphates. 2. 2-Methyl-3-hydroxyindan-1-on-3-yl dialkylphosphonates upon reaction with thionyl chloride are transformed to 2-methylind-2-en-1-on-3-yl dialkylphosphonates. 3. Reaction of 2-methylindane-1,3-dione with diethylphosphorous acid in excess triethylamine at 160° proceeds complexly with formation of 2-methylind-2-en-1-on-3-yl diethylphosphate and a series of products not containing phosphorous. Unsaturated dialkyl phosphates were also obtained from 2-bromo-2-methylindane-1,3-dione and trialkyl phosphites. 4. 2-Methylind-2-en-1-one reacts with diethylphosphorous acid in the presence of triethylamine with formation of 2-methyl-1-hydroxyind-2-en-1-yl diethylphosphonate. © 1976 Plenum Publishing Corporation. |
|
dc.relation.ispartofseries |
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science |
|
dc.title |
Reaction of dialkylphosphorous acids with 2-methylindane-1,3-dione |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
5 |
|
dc.relation.ispartofseries-volume |
25 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1088 |
|
dc.source.id |
SCOPUS05685230-1976-25-5-SID34250297406 |
|