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Study of the spatial structure of the chloroanhydride of dichloromethylphosphonic acid by a combination of various physical methods

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dc.contributor.author Raevskii O.
dc.contributor.author Khalitov F.
dc.contributor.author Mumzhieva N.
dc.contributor.author Gilyazov M.
dc.contributor.author Zakirov D.
dc.contributor.author Safin I.
dc.contributor.author Aganov A.
dc.date.accessioned 2018-09-14T20:31:45Z
dc.date.available 2018-09-14T20:31:45Z
dc.date.issued 1976
dc.identifier.issn 0568-5230
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/132543
dc.description.abstract 1. In the liquid state, in solution, and in one of its crystalline modifications, the chlorohydrate of dichloromethylphosphonic acid exists as a mixture of two nonrotating isomers of Cs and C1 symmetries (gauche-gauche and gauche-trans orientation of the two CHCl2 group chlorines with respect to the P=O bond). The conformers are individually stabilized in the other crystalline modifications. 2. It is assumed that weak intramolecular bonds of the C-H...O=P type play a role in the stabilizing the conformer with the chlorine in the gauche-trans orientation. © 1977 Plenum Publishing Corporation.
dc.relation.ispartofseries Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
dc.title Study of the spatial structure of the chloroanhydride of dichloromethylphosphonic acid by a combination of various physical methods
dc.type Article
dc.relation.ispartofseries-issue 12
dc.relation.ispartofseries-volume 25
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 2514
dc.source.id SCOPUS05685230-1976-25-12-SID34250289093


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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