Kazan Federal University Digital Repository

Anomalous reactions of sodium diethyl phosphite and of triethyl phosphite with some halogenated derivates

Show simple item record

dc.contributor.author Arbuzov B.
dc.contributor.author Bogonostseva N.
dc.date.accessioned 2018-09-14T20:18:18Z
dc.date.available 2018-09-14T20:18:18Z
dc.date.issued 1954
dc.identifier.issn 0568-5230
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/132324
dc.description.abstract 1. Dinaphthylchloromethane, dinaphthylbromomethane, 9-chlorofluorine and 9-bromofluorine did not react in the experimental conditions. 2. Phenanthrene was formed by reaction of sodium diethyl phosphite and triethyl phosphite with 9,10-dibromophenanthrene. 3. Dibenzoylbromomethane and tribenzoylbromomethane react with sodium diethyl phosphite or with triethyl phosphite with formation of dibenzoylmethane and tribenzoylmethane, 4. Bromoindandione and the ethyl ester of bromoindandionecalboxylic acid react with sodium diethyl phosphite or with triethyl phosphite with formation of indandione or of products of dimerization of the free indandionyl radical. 5. The most probable reaction scheme, which explains the anomalous course of the bromo compounds with sodium diethyl phosphite or triethyl phosphate, is one involving the assumption of formation of free radicals as intermediate products. © 1954 Consultants Bureau, Inc.
dc.relation.ispartofseries Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
dc.title Anomalous reactions of sodium diethyl phosphite and of triethyl phosphite with some halogenated derivates
dc.type Article
dc.relation.ispartofseries-issue 5
dc.relation.ispartofseries-volume 3
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 723
dc.source.id SCOPUS05685230-1954-3-5-SID34250582488


Files in this item

This item appears in the following Collection(s)

  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

Show simple item record

Search DSpace


Advanced Search

Browse

My Account

Statistics