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Dipole moments of N,N-diethyl(dialkoxyphosphinyl)formamides

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dc.contributor.author Arbuzov B.
dc.contributor.author Shavsha T.
dc.date.accessioned 2018-09-14T20:17:20Z
dc.date.available 2018-09-14T20:17:20Z
dc.date.issued 1952
dc.identifier.issn 0568-5230
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/132305
dc.description.abstract 1. Dipole-moment measurements have been made on six N,N-diethyl(dialkoxyphosphinyl)formamides. The mean value obtained for the dipole moments is 2.96 D, which is close to the value calculated on the assumption of free rotation of ] the irregular groups (μ = 3.33 D). 2. Calculation of the interatomic distances between, individual groups in N,N-diethyl(dialkoxyphosphinylformamides, taking into account the free rotation of the irregular groups, shows, however, the presence of a great measure of overlap of the spheres of action of Van der Waals forces due to methyl and methylene groups, and this makes it improbable that free rotation of the irregular groups can occur. 3. It is more probable that there is a synchronous vibration of OR and[Figure not available: see fulltext.] groups, having an amplitude of 180°. © 1953 Consultants Bureau.
dc.relation.ispartofseries Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
dc.title Dipole moments of N,N-diethyl(dialkoxyphosphinyl)formamides
dc.type Article
dc.relation.ispartofseries-issue 5
dc.relation.ispartofseries-volume 1
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 781
dc.source.id SCOPUS05685230-1952-1-5-SID34250594879

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  • Публикации сотрудников КФУ Scopus [20180]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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