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Accuracy of determination of self-diffusion coefficients in studies of porphyrin-based complexes by 2D DOSY

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dc.contributor.author Khodov I.
dc.date.accessioned 2018-04-05T07:10:14Z
dc.date.available 2018-04-05T07:10:14Z
dc.date.issued 2017
dc.identifier.issn 1998-9539
dc.identifier.uri http://dspace.kpfu.ru/xmlui/handle/net/130302
dc.description.abstract © ISUCT Publishing. Influence of chemical exchange processes on the accuracy of determination of self-diffusion complexes of porphyrinnickel complexes was shown. A method of estimating the inaccuracy of the self-diffusion coefficients for an inverted porphyrin complex was proposed. The values obtained using two different approaches to recording DOSY spectra, STE and CPMG, were compared. Allowing for exchange was shown to be important for accurate diffusion measurements and correct interpretation of results obtained in studied of molecular-level processes.
dc.relation.ispartofseries Macroheterocycles
dc.subject 2D DOSY
dc.subject Chemical exchange
dc.subject J-modulation
dc.subject N-confused porphyrins
dc.subject NMR
dc.subject Self-diffusion coefficients
dc.title Accuracy of determination of self-diffusion coefficients in studies of porphyrin-based complexes by 2D DOSY
dc.type Article
dc.relation.ispartofseries-issue 3
dc.relation.ispartofseries-volume 10
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 313
dc.source.id SCOPUS19989539-2017-10-3-SID85038111591


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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