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dc.contributor.author | Yakimova L. | |
dc.contributor.author | Gilmanova L. | |
dc.contributor.author | Evtugyn V. | |
dc.contributor.author | Osin Y. | |
dc.contributor.author | Stoikov I. | |
dc.date.accessioned | 2018-04-05T07:09:51Z | |
dc.date.available | 2018-04-05T07:09:51Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 1388-0764 | |
dc.identifier.uri | http://dspace.kpfu.ru/xmlui/handle/net/130011 | |
dc.description.abstract | © Springer Science+Business Media Dordrecht 2017. Novel water-soluble anionic p-tertbutylthiacalix[ 4]arene with propanesulfonate fragments has been synthesized. Alkylation of the lower rim of thiacalix[4] arene in the presence of NaH/THF led to cone conformation instead of the expected 1,3-alternate conformer due to metal template effect. The presence of supramolecular associates at the critical micelle concentration of 1.65 · 10 −5 M were investigated in aqueous solutions by a combination of different techniques (DLS and conductivity). It was observed that the macrocyclic platform decreases the CMC by tenfold as compared with non-macrocycle analogs. A simple approach for the design of stable monodisperse Ag-based nanoaggregates (near 95 nm) containing ionic Ag and organic ligand-thiacalix[4]arene sulfo derivative in water has been developed. Self-assembled fractal hybrid nanodendrites consisting of water-soluble anionic (thia)calix[4] arenes and Ag + have been obtained in a single step under mild conditions. | |
dc.relation.ispartofseries | Journal of Nanoparticle Research | |
dc.subject | (Thia)calix[4]arene | |
dc.subject | Ag-based aggregates | |
dc.subject | Dendrite | |
dc.subject | Electron microscopy | |
dc.subject | Mapping | |
dc.subject | Self-assembly | |
dc.subject | Stable suspensions | |
dc.title | Self-assembled fractal hybrid dendrites from water-soluble anionic (Thia)calix[4] arenes and Ag<sup>+</sup> | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 5 | |
dc.relation.ispartofseries-volume | 19 | |
dc.collection | Публикации сотрудников КФУ | |
dc.source.id | SCOPUS13880764-2017-19-5-SID85025439847 |