dc.contributor.author |
Puls F. |
|
dc.contributor.author |
Richter N. |
|
dc.contributor.author |
Kataeva O. |
|
dc.contributor.author |
Knölker H. |
|
dc.date.accessioned |
2018-04-05T07:09:26Z |
|
dc.date.available |
2018-04-05T07:09:26Z |
|
dc.date.issued |
2017 |
|
dc.identifier.issn |
0947-6539 |
|
dc.identifier.uri |
http://dspace.kpfu.ru/xmlui/handle/net/129736 |
|
dc.description.abstract |
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim We have developed a short and simple synthesis of tetranuclear palladium(II) complexes that have been structurally confirmed by X-ray analysis. These complexes were formed in about 30 % overall yield by spontaneous metalation of dimethylaminoarene derivatives and exhibit a high stability. We have studied the utility of the tetranuclear palladium(II) complexes as precatalysts for Mizoroki–Heck and Suzuki–Miyaura cross-coupling reactions. Our novel complexes show excellent catalytic activities with high turnover numbers (TON) and high turnover frequencies (TOF) (e.g., for the Suzuki–Miyaura reaction: TON up to 538000 and TOF up to 23400 h −1 at room temperature). |
|
dc.relation.ispartofseries |
Chemistry - A European Journal |
|
dc.subject |
catalysis |
|
dc.subject |
Mizoroki–Heck coupling |
|
dc.subject |
palladacycles |
|
dc.subject |
Suzuki–Miyaura coupling |
|
dc.subject |
X-ray diffraction |
|
dc.title |
Synthesis of Tetranuclear Palladium(II) Complexes and Their Catalytic Activity for Cross-Coupling Reactions |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
69 |
|
dc.relation.ispartofseries-volume |
23 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
17576 |
|
dc.source.id |
SCOPUS09476539-2017-23-69-SID85034264916 |
|