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dc.contributor.author | Fujiki K. | |
dc.contributor.author | Tanaka K. | |
dc.date.accessioned | 2018-04-05T07:09:11Z | |
dc.date.available | 2018-04-05T07:09:11Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 0039-7881 | |
dc.identifier.uri | http://dspace.kpfu.ru/xmlui/handle/net/129565 | |
dc.description.abstract | Copyright © 2017, Georg Thieme Verlag. All rights reserved. A previously unreported 1,5-diazacyclooctane-palladium(II) complex was synthesized using bis[ N , N ′-(2-indanolyl)]-1,5-diazacyclooctane, which was readily prepared via a novel [4+4] homocyclization of the unsaturated imine intermediate generated from acrolein and 1-amino-2-indanol. Interestingly, the 1,5-diazacyclooctane-palladium(II) complex self-assembled to form palladium nanoparticles. This approach readily provided palladium nanoparticles simply by heating a mixture of palladium(II) acetate and bis[ N , N ′-(2-indanolyl)] -1,4-diazacyclooctane in dichloroethane at mild temperatures. The 1,5-diazacyclooctane-derivative-palladium nanoparticles were successfully deployed in synthetic applications as a heterogeneous catalyst, facilitating Suzuki coupling and a challenging C–C bond formation via C(sp 3 )–H activation under low catalyst loading conditions. | |
dc.relation.ispartofseries | Synthesis (Germany) | |
dc.subject | 1,5-diazacyclooctane | |
dc.subject | C(sp )–H activation 3 | |
dc.subject | chiral ligand | |
dc.subject | heterogeneous catalyst | |
dc.subject | palladium nanoparticles | |
dc.subject | Suzuki coupling | |
dc.title | Bis[ N , N ′-(2-indanolyl)]-1,5-diazacyclooctane as Unique Metal Ligand: Self-Assembly of Palladium Nanoparticles and Catalytic Reactivity on C–C Bond Formation | |
dc.type | Article in Press | |
dc.collection | Публикации сотрудников КФУ | |
dc.source.id | SCOPUS00397881-2017-SID85034058725 |