Browsing by Subject "crown ethers"

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Thiocyanate Coordination to the {Ta<inf>6</inf>I<inf>12</inf>}<sup>2+</sup> Cluster. Preparation and Crystal Structure of [K(Dibenzo-24-Crown-8)(CH<inf>3</inf>COCH<inf>3</inf>)]<inf>2</inf>(Ph<inf>4</inf>P)<inf>2</inf>[Ta<inf>6</inf>I<inf>12</inf>(NCS)<inf>6</inf>]

Shamshurin M.V.; Sukhikh T.S.; Mikhailov M.A.; Sheven D.G.; Sokolov M.N. (2020)

© 2020, Pleiades Publishing, Ltd. The reaction of Ta6I14 with KNCS in acetonitrile in the presence of 24-dibenzo-crown-8 leads to dissolution of the tantalum iodide cluster to form the [Ta6I12(NCS)6]4− complex. By evaporation ...

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