Solomonov B.; Zaitseva K.; Varfolomeev M.; Sedov I.(2011)
We propose a method for calculating the Gibbs energies of hydrogen bonding of solutes with associated solvents via the thermodynamic analysis of experimental values of solvation Gibbs energies. The method is applied to ...
A method for analyzing the thermodynamical manifestations of solvophobic effects is proposed on the basis of considering the relationship between the Gibbs energy and solvation enthalpy of nonelectrolytes. It is demonstrated ...
A new method was suggested for estimating the hydrophobic effect of contributions to the Gibbs energies and enthalpies of hydration of hydrocarbons, inorganic gases and rare gases. In accordance with this method the ...
The magnitudes of the Gibbs free energies of self-association for several primary aliphatic alcohols at 298 K are calculated. The fraction of monomeric molecules in bulk alcohols is determined. We started from the experimental ...
An approach is suggested to describe the solvophobic effects in various solvents, qualitatively and quantitatively. We analyzed the relationships between the Gibbs energies and enthalpies of solvation of alkanes in various ...
A new method of experimental determination of thermodynamic functions of the hydrophobic effect is proposed. It is based on regarding the thermodynamic functions of hydration as the sum of thermodynamic functions of ...
Reactivity and equilibrium properties of organic molecules in self-associated liquids greatly depend on the hydrogen bonding with solvent. This work contains comprehensive thermodynamic analysis of hydrogen bonding of ...
The properties of solutes and their reactivity in aliphatic alcohols significantly depend on the formation of hydrogen bonds. In this work, calorimetric, FTIR-spectroscopic and gas chromatographic vapor pressure studies ...