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Diels–Alder Reaction as an Indicator of Internal and External Factors Influencing the Rate and Equilibrium: Kinetics, Thermochemistry, Catalysis, and High Pressure. A Review

Konovalov A.I.; Kornilov D.A.; Kiselev V.D. (2021)

Abstract: The Diels–Alder reaction (DAR), in addition to its enormous synthetic potential, is the most reliable testing ground for quantitative research of the influence of various internal and external factors on the rate ...
Effect of hydrostatic pressure, temperature, and solvent on the rate of the Diels–Alder reaction between 9,10-anthracenedimethanol and maleic anhydride

Kiselev V.; Kornilov D.; Anikin O.; Latypova L.; Konovalov A. (2017)

© 2017, Pleiades Publishing, Ltd.The rate of the reaction between 9,10-anthracenedimethanol and maleic anhydride in 1,4-dioxane, acetonitrile, trichloromethane, and toluene is studied at 25, 35, 45°C in the pressure range ...
High pressure influence on the Diels–Alder reaction volume in the solid phase at pressure up to 7000 bar and in solution

Kornilov D.; Dinikaev I.; Kiselev V. (2019)

© 2019, © 2019 Informa UK Limited, trading as Taylor & Francis Group. The molar volumes of tetracyanoethylene (1), maleic anhydride (2), N-phenylmaleimide (3), anthracene (4), trans, trans-1,4-diphenyl-1,3-butadiene (5), ...
Reactivity Variation of Tetracyanoethylene and 4-Phenyl-1,2,4-Triazoline-3,5-Dione in Cycloaddition Reactions in Solutions

Kiselev V.; Kornilov D.; Anikin O.; Shulyatiev A.; Konovalov A. (2019)

© 2019, Springer Science+Business Media, LLC, part of Springer Nature. The reasons for the very high reactivity and variability of reactivity of two dienophiles, tetracyanoethylene (1) and 4-phenyl-1,2,4-triazoline-3,5-dione ...
Sharp difference in the rate of formation and stability of the Diels–Alder reaction adducts with 2,3-dicyano-1,4-benzoquinone and N-phenylimide-1,4-benzoquinone-2,3-dicarboxylic acid

Kiselev V.D.; Kolesnikova A.O.; Shulyatiev A.A.; Dinikaev I.F.; Kornilov D.A. (2021)

This work reports new studies of the activity and Diels–Alder kinetics of a series of dienophiles: tetracyanoethylene (1), 2,3-dicyano-p-benzoquinone (10), and N-phenylimide-1,4-benzoquinone-2,3-dicarboxylic acid (11). ...
Stereochemistry of hexachlorocyclopentadiene [4+2]-cycloaddition to 2-substituted 4,7-dihydro-1,3-dioxepins

Pavelyev R.; Vafina R.; Lodochnikova O.; Galiullina A.; Romanova E.; Balakin K.; Shtyrlin Y. (2016)

© 2016 Elsevier LtdExperimental investigation of hexachlorocyclopentadiene [4+2]-cycloaddition to 2-substituted 4,7-dihydro-1,3-dioxepins revealed an atypical stereochemical effect. Clear experimental evidence was obtained ...
Structure–reactivity relationship in Diels–Alder reactions obtained using the condensed reaction graph approach

Madzhidov T.; Gimadiev T.; Malakhova D.; Nugmanov R.; Baskin I.; Antipin I.; Varnek A. (2017)

© 2017, Pleiades Publishing, Ltd. By the structural representation of a chemical reaction in the form of a condensed graph a model allowing the prediction of rate constants (logk) of Diels–Alder reactions performed in ...
СИНТЕЗ И РЕНТГЕНОСТРУКТУРНЫЙ АНАЛИЗ АДДУКТА ТИОФЕНА В РЕАКЦИИ ДИЛЬСА – АЛЬДЕРА С МАЛЕИНОВЫМ АНГИДРИДОМ // Ученые записки КФУ. Естественные науки 2012 том154 N3

Киселев Владимир Дмитриевич; Шакирова Ильзида Исхаковна; Корнилов Дмитрий Анатольевич; Литвинов Игорь Анатольевич; Коновалов Александр Иванович (2012)

Методом рентгеноструктурного анализа доказано, что структура аддукта реакции Дильса – Альдера между тиофеном и малеиновым ангидридом, полученного при давлении 8 кбар и температуре 100 °C, соответствует exo -изомеру.

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Browsing by Subject "Diels–Alder reaction"

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