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A "sodium trap" based on benzo-15-crown-5 with an exocyclic N-(thiophosphoryl)thiourea moiety

Sokolov F.; Safin D.; Babashkina M.; Zabirov N.; Brusko V.; Mironov N.; Krivolapov D.; Litvinov I.; Cherkasov R.; Solomonov B. (2007)

For N-(thio)phosphorylthioureas of the common formula RC(S)NHP(X)(OiPr)2 HLI (R = N-(4′-aminobenzo-15-crown-5), X = S), HLII (R = N-(4′-aminobenzo-15-crown-5), X = O), HLIII (R = PhNH, X = S), HLIV (R = PhNH, X = O), and ...
Complexes of crown ether-containing N-phosphorylated thioamides and thioureas with CoII, ZnII and PdII cations

Safin D.; Babashkina M.; Sokolov F.; Baranov S.; Ekkehardt Hahn F.; Pape T. (2009)

The reaction of the potassium salts of N-phosphorylated thioureas [4'-benzo-15-crown-5]NHC(S)NHP(Y)(OiPr)2 (Y = S, HLI; Y = O, HLII) with ZnII and CoII cations in aqueous EtOH leads to complexes of formulae Zn(LI,IIS,Y)2 ...
Complexes of N-thiophosphorylthiourea tBuNHC(S)NHP(S)(OiPr)2 with zinc(II), cadmium(II), nickel(II), and cobalt(II) cations

Safin D.; Sokolov F.; Gimadiev T.; Brusko V.; Babashkina M.; Chubukaeva D.; Krivolapov D.; Litvinov I. (2008)

Reaction of the potassium salt of N-thiophosphorylthiourea tBuNHC(S)NHP(S)(OiPr)2 (HL) with ZnII, CdII, NiII and CoII in aqueous EtOH leads to complexes of common formula M(L-S,S′)2 (ML2). Complexes were investigated by ...
Complexes of N-thiophosphorylthiourea α-naphthylnhc(S)NHP(S)(OiPr)2 (HL) with copper(I). crystal structures of HL and Cu(PPh3)2L

Babashkina M.; Safin D.; Szyrwiel Ł.; Kubiak M.; Sokolov F.; Starikov Y.; Kozlowski H. (2009)

Reaction of the potassium salt of N-thiophosphorylated thiourea α-naphthylNHC(S)NHP(S)(OiPr)2 (HL) with Cu(PPh3)3I in aqueous EtOH/CH2Cl2 leads to the mononuclear complex [Cu(PPh3)2L-S,S′]. By using copper(I) iodide instead ...
Coordination mode of the nickel(II) cation with N-diisopropoxyphosphinyl-p- bromothiobenzamide

Safin D.; Sokolov F.; Baranov S.; Szyrwiel Ł.; Babashkina M.; Shakirova E.; Hahn F.; Kozlowski H. (2008)

Reaction of the potassium salt of N-diisopropoxyphosphinyl-p- bromothiobenzamide p-BrC6H4C(S)NHP(O)(OiPr)2 (HL) with Ni(NO3)2 in aqueous EtOH leads to complex of formula [Ni(HL-O)2(L-O,S)2] (1). The structure of 1 was ...
Coordination mode of the zinc(II) and cadmium(II) cations with N-(diisopropoxyphosphoryl)thiobenzamide

Sokolov F.; Safin D.; Zabirov N.; Brusko V.; Khairutdinov B.; Krivolapov D.; Litvinov I. (2006)

Reaction of the potassium salt of N-(diisopropoxyphosphoryl)thiobenzamide (iPrO)2P(O)NHC(S)C6H5 (HL) with ZnII and CdII cations in aqueous EtOH leads to three different complexes: [Zn(L-O,S)2] (1), [Cd2(L-O,S)4] (2) and ...
Crystal structure and dynamic behavior of [Ni{PhNHC(S)NP(S)(OPr i)2-S,S}2] complex in dichloromethane solution

Brusko V.; Rakhmatullin A.; Shtyrlin V.; Krivolapov D.; Litvinov I.; Zabirov N. (2006)

The crystal structure of the complex [Ni{PhNHC(S)NP(S)(OPr i)2-S,S}2] has been determined and its behavior in dichloromethane solution investigated by NMR 31P spectroscopy. The X-ray structural analysis shows the nickel ...
Self-assembly of the complexes of bipodal thiophosphorylated thioureas

Zabirov N.; Brusko V.; Verat A.; Krivolapov D.; Litvinov I.; Cherkasov R. (2002)

N-Thiophosphorylated thioureas, of general formula [(i-PrO)2 P(S)NHC(S)]2Z (Z = α,ω-diamino(oxy)alkyl or 1,10-diaza-18-crown-6), in the form of potassium salts, react with a number of soft ions (Cd2+, Zn2+, Co2+, Ni2+, ...
Zn(II), Co(II) and Ni(II) complexes of a phosphorylthiourea derivative of 4-[(EtO)2P(O)CH2]-C6H4-NHC(S)NHP(O) (OiPr)2

Babashkina M.; Safin D. (2010)

The reaction of O,O'-diisopropyl phosphorisothiocyanatidate, (iPrO) 2P(O)NCS, with diethyl-(4-aminobenzyl)phosphonate leads to the new N-phosphorylated thiourea derivative, 4-[(EtO)2P(O)CH 2]-C6H4NHC(S)NHP(O)(OiPr)2 (HL). ...

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