Главная
→
Просмотр по теме

Просмотр по теме "Enthalpy of solvation"

Отображаемые элементы 1-20 из 29

Следующая страница

Additive scheme of solvation enthalpy for linear, cyclic and branched-chain aliphatic compounds at 298.15 K

Nagrimanov R.; Samatov A.; Solomonov B. (2019)

© 2019 Elsevier B.V. In this work, an additive scheme for the estimation of solvation enthalpy of saturated and unsaturated aliphatic hydrocarbons, alcohols, ketones, aldehydes and nitriles in n-heptane was developed. The ...
Analysis of solute-pyridine intermolecular interactions based on experimental enthalpies of solution and enthalpies of solvation of solutes dissolved in pyridine

Неизвестный автор (2018)

© 2017 Elsevier B.V. In present work thermochemistry of solvation of inert gases and organic solutes in pyridine was thoroughly studied using solution calorimetry technique. Enthalpies of solution at infinite dilution of ...
Determination of sublimation enthalpies of substituted benzophenones, fluorenes and diphenyl ethers by solution calorimetry approach

Nagrimanov R.; Samatov A.; Buzyorov A.; Solomonov B. (2017)

© 2017 Elsevier B.V. An approach for the determination of solvation enthalpies of substituted aromatic compounds is developed. In this work the solvation enthalpy of a reference unit (benzophenone, fluorene and diphenyl ...
Development of Abraham model correlations for enthalpies of solvation of solutes dissolved in N-methylformamide, 2-pyrrolidone and N-methylpyrrolidone

Magsumov T.I.; Sedov I.A.; Acree W.E. (2021)

Enthalpies of solution at infinite dilution have been determined for 2-propanol, ethylene glycol, 1,3-butanediol, 1,4-butanediol, phenol, 1-naphthol, 3-nitrophenol, 4-nitrophenol, 4-chlorophenol, and formamide dissolved ...
Effect of halogen substitution on the enthalpies of solvation and hydrogen bonding of organic solutes in chlorobenzene and 1,2-dichlorobenzene derived using multi-parameter correlations

Varfolomeev M.; Rakipov I.; Khachatrian A.; Acree W.; Brumfield M.; Abraham M. (2015)

© 2015 Elsevier B.V. Enthalpies of solution at infinite dilution at 298 K, Δ<inf>soln</inf>H<sup>A/Solvent</sup>, have been measured by isothermal solution calorimetry for 43 and 72 organic solutes dissolved in chlorobenzene ...
Enthalpies and Gibbs free energies of solvation in ethylene glycol at 298K: Influence of the solvophobic effect

Sedov I.; Stolov M.; Solomonov B. (2013)

Enthalpies of solution of low-polar substances: aliphatic and aromatic hydrocarbons, including alkanes, cycloalkanes, alkylbenzenes, naphthalene, biphenyl, and halobenzenes in ethylene glycol were measured at temperature ...
Enthalpies of fusion and enthalpies of solvation of aromatic hydrocarbons derivatives: Estimation of sublimation enthalpies at 298.15 K

Solomonov B.; Nagrimanov R.; Varfolomeev M.; Buzyurov A.; Mukhametzyanov T. (2016)

© 2016 Elsevier B.V. All rights reserved.Enthalpy of sublimation of solid compound can be found using the values of solution enthalpy and solvation enthalpy in any solvent. In this work enthalpies of solution at infinite ...
Enthalpies of solution and enthalpies of solvation in water: The anion effect in ionic liquids with common 1-ethyl-3-methyl-imidazolium cation

Varfolomeev M.; Khachatrian A.; Akhmadeev B.; Solomonov B.; Yermalayeu A.; Verevkin S. (2015)

© Springer Science+Business Media New York 2015. Abstract Thermochemical studies of ionic liquids (ILs) in aqueous solution were carried out using solution calorimetry. Heat effects of dissolution in water at 298.15 K and ...
Enthalpies of solution and enthalpies of solvation in water: The anion effect in ionic liquids with common 1-ethyl-3-methyl-imidazolium cation

Varfolomeev Mikhail Alekseevich; Khachatrian Artashes Abraamovich; Ahmadeev Bulat Salavatovich; Solomonov Boris Nikolaevich; Yermalayeu Andrei Vladimerovich; Verevkin Sergej Petrovich; Ahmadeev Bulat Salavatovich; Hachatryan Artashes Abraamovich (2015)
Enthalpies of solution and enthalpies of solvation of chloro- and nitro-substituted benzenes in 1-butyl-3-methyl imidazolium based ionic liquids at 298.15 K: Additivity of group contributions

Khachatrian A.; Shamsutdinova Z.; Varfolomeev M. (2016)

© 2016 Elsevier B.V.In this work thermochemistry of solution and solvation of mono- and di-substituted chloro- and nitro-benzenes in 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]), 1-butyl-3-methylimidazolium ...
Enthalpies of solution and enthalpies of solvation of organic solutes in ethylene glycol at 298.15 K: Prediction and analysis of intermolecular interaction contributions

Stolov M.; Zaitseva K.; Varfolomeev M.; Acree W. (2017)

© 2016 Elsevier B.V.Ethylene glycol is one of the most usually used liquid media for realization of different industrial processes. In present work thermochemistry of solvation of inert gases and organic solutes in ethylene ...
Enthalpies of solution, enthalpies of fusion and enthalpies of solvation of polyaromatic hydrocarbons: Instruments for determination of sublimation enthalpy at 298.15K

Solomonov B.; Varfolomeev M.; Nagrimanov R.; Mukhametzyanov T.; Novikov V. (2015)

© 2015. In this work a simple method for calculation of solvation enthalpies of polyaromatic hydrocarbons (PAHs) in various solvents at 298.15. K was proposed. According to this method the enthalpy of solvation of any ...
Enthalpies of sublimation and vaporization of poly-substituted phenols containing intramolecular hydrogen bonds by solution calorimetry method

Nagrimanov R.N.; Ibragimova A.R.; Solomonov B.N. (2020)

© 2020 Elsevier B.V. A simple procedure for calculation of solvation enthalpy of compounds containing intramolecular hydrogen bond was developed. This procedure is based on the assumption that fragments of molecules ...
Enthalpy of solvation correlations for organic solutes and gases dissolved in dichloromethane and 1,4-dioxane

Wilson A.; Tian A.; Dabadge N.; Acree W.; Varfolomeev M.; Rakipov I.; Arkhipova S.; Abraham M. (2013)

Enthalpies of solution at infinite dilution of 53 organic solutes in dichloromethane and 10 organic solutes in 1,4-dioxane were measured using semi-adiabatic solution calorimeter. Enthalpies of solvation for 103 organic ...
Examination of hydrogen-bonding interactions between dissolved solutes and alkylbenzene solvents based on Abraham model correlations derived from measured enthalpies of solvation

Varfolomeev M.; Rakipov I.; Acree W.; Brumfield M.; Abraham M. (2014)

© 2014 Elsevier B.V. All rights reserved. Enthalpies of solution at infinite dilution of 48 organic solutes in mesitylene and 81 organic solutes in p-xylene were measured using isothermal solution calorimeter. Enthalpies ...
Group additive approach for heterocyclic aromatic solutes in [BMIM][BF<inf>4</inf>]

Khachatrian A.A.; Yakhvarov D.G.; Sinyashin O.G.; Rakipov I.T.; Mukhametzyanov T.A.; Solomonov B.N. (2021)

This work continues the development of the additive scheme for the calculation of solvation enthalpies of aromatic compounds in 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]). In this study, heterocyclic ...
Group additivity approach for determination of solvation enthalpies of aromatic compounds in 1-butyl-3-methylimidazolium tetrafluoroborate based on solution calorimetry data

Khachatrian A.; Shamsutdinova Z.; Varfolomeev M. (2017)

© 2017 Elsevier B.V.In this work thermochemistry of solvation of mono-, di-, tri- and tetra-substituted benzenes in 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]) ionic liquid was studied. Enthalpies of solution ...
Modified solution calorimetry approach for determination of vaporization and sublimation enthalpies of branched-chain aliphatic and alkyl aromatic compounds at T = 298.15 K

Varfolomeev M.; Novikov V.; Nagrimanov R.; Solomonov B. (2015)

© 2015 Elsevier Ltd. All rights reserved. The enthalpies of solution, solvation and vaporization/sublimation are interrelated values combined in the simplest thermodynamic circle. Hence, experimental determination of ...
New method for determination of vaporization and sublimation enthalpy of aromatic compounds at 298.15 K using solution calorimetry technique and group-additivity scheme

Solomonov B.; Varfolomeev M.; Nagrimanov R.; Novikov V.; Buzyurov A.; Fedorova Y.; Mukhametzyanov T. (2015)

© 2015 Elsevier B.V. All rights reserved. In this work a new method for determination of vaporization/sublimation enthalpies of aromatic compounds directly at T = 298.15 K was developed. This method is based on the general ...
Non-additivity in the solvation enthalpies of NH-containing compounds and estimation of their sublimation enthalpies at 298 K

Nagrimanov R.; Samatov A.; Nasyrova T.; Solomonov B. (2017)

© 2017 Elsevier B.V. In the present work, we have developed an additivity scheme for the calculation of solvation enthalpies of NH-containing compounds capable of hydrogen bond formation with solvent. The solvation enthalpies ...

Отображаемые элементы 1-20 из 29

Следующая страница

Поиск в электронном архиве

Расширенный поиск

Просмотр

Весь электронный архив

Просмотр по теме "Enthalpy of solvation"

Просмотр по теме "Enthalpy of solvation"

Поиск в электронном архиве

Просмотр

Весь электронный архив

Моя учетная запись